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NEET Thermodynamics: MCQs, Solutions & Revision

Practice Thermodynamics for NEET with chapter-wise MCQs, stepwise solutions, quick revision notes and related mock tests.

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Thermodynamics Revision Guide for NEET Chemistry

Thermodynamics relates heat, work, internal energy, enthalpy and spontaneity. It is best learned through sign conventions and state-function logic rather than isolated memorisation.

For NEET Chemistry, revise the first law, enthalpy changes, Hess law, entropy and Gibbs free energy, then practise conceptual and numerical MCQs together.

Important Topics

  • System, surroundings and state functions
  • First law of thermodynamics
  • Enthalpy and heat capacity
  • Hess law
  • Entropy
  • Gibbs free energy and spontaneity

Important Formulae & Relationships

  • ΔU = q + w
  • At constant pressure: qp = ΔH
  • ΔH = ΔU + ΔngRT (for ideal-gas reactions)
  • ΔG = ΔH − TΔS
  • ΔG° = −RT ln K

Use formulas only after checking the required units, sign convention and assumptions for the question.

What to practise in Thermodynamics

Concept Revision

Revise definitions, principles, equations, trends and core ideas from Thermodynamics before attempting MCQs.

Exam-style MCQs

Use chapter-focused multiple-choice practice to improve accuracy, recall and application for NEET Chemistry.

Performance Practice

Attempt ChemNexa tests, review results and return to weak areas for another round of targeted revision.

Top 20 Thermodynamics MCQs with Answers

These public questions are selected from the exact Thermodynamics chapter, screened for topic relevance and deduplicated so repeated versions of the same MCQ are not shown publicly. Use them for quick revision, then sign in to attempt the complete test experience with more questions, results and performance review.

NEET Chemistry · Thermodynamics · Very Very Hard

1. For a spontaneous process at constant T and P in a Thermodynamics context, ΔG is:

  • A. Negative
  • B. Positive
  • C. Always zero
  • D. Always equal to ΔH
Answer: A
Explanation: Spontaneity at constant T,P requires ΔG<0.

NEET Chemistry · Thermodynamics · Very Very Hard

2. Which is a state function useful in Thermodynamics?

  • A. Work
  • B. Path length
  • C. Enthalpy
  • D. Heat
Answer: C
Explanation: Enthalpy is path independent.

NEET Chemistry · Thermodynamics · Very Very Hard

3. The relation between standard Gibbs energy and equilibrium constant is:

  • A. ΔG°=RT/K
  • B. ΔG°=-RT lnK
  • C. ΔG°=RT lnK
  • D. ΔG°=-KRT
Answer: B
Explanation: The standard thermodynamic relation is ΔG°=-RT lnK.

NEET Chemistry · Thermodynamics · Very Very Hard

4. A positive E°cell implies:

  • A. No spontaneous reaction
  • B. ΔG°<0
  • C. ΔG°>0
  • D. K<1 necessarily
Answer: B
Explanation: ΔG°=-nFE°.

NEET Chemistry · Thermodynamics · Very Very Hard

5. Which principle is essential when solving a quantitative problem in Thermodynamics?

  • A. Assuming all coefficients are unity
  • B. Ignoring limiting conditions
  • C. Conservation of mass and charge where applicable
  • D. Ignoring units
Answer: C
Explanation: Mass and charge conservation are fundamental.

NEET Chemistry · Thermodynamics · Very Very Hard

6. At equilibrium in a reversible system related to Thermodynamics, which statement is correct?

  • A. The catalyst is consumed
  • B. Forward and reverse rates are equal
  • C. All molecular motion stops
  • D. Reactant and product concentrations must be equal
Answer: B
Explanation: Dynamic equilibrium has equal forward and reverse rates.

NEET Chemistry · Thermodynamics · Very Very Hard

7. Which statement about a catalyst in Thermodynamics is correct?

  • A. It changes ΔG°
  • B. It changes reaction enthalpy
  • C. It is always consumed
  • D. It lowers the activation barrier without changing K at fixed T
Answer: D
Explanation: Catalysts affect kinetics, not equilibrium thermodynamics.

NEET Chemistry · Thermodynamics · Very Very Hard

8. Oxidation in a redox step relevant to Thermodynamics means:

  • A. No oxidation-number change
  • B. Only gain of hydrogen
  • C. Loss of electrons
  • D. Gain of electrons
Answer: C
Explanation: Oxidation is electron loss.

NEET Chemistry · Thermodynamics · Very Very Hard

9. Reduction in a redox step relevant to Thermodynamics means:

  • A. Only loss of hydrogen
  • B. Gain of electrons
  • C. Loss of electrons
  • D. Increase in oxidation number
Answer: B
Explanation: Reduction is electron gain.

NEET Chemistry · Thermodynamics · Very Very Hard

10. A Lewis acid encountered in Thermodynamics is an:

  • A. Electron-pair acceptor
  • B. Electron-pair donor
  • C. Proton acceptor only
  • D. Anion only
Answer: A
Explanation: Lewis acids accept electron pairs.

NEET Chemistry · Thermodynamics · Very Very Hard

11. A Lewis base encountered in Thermodynamics is an:

  • A. Electron-pair acceptor
  • B. Cation only
  • C. Oxidising agent only
  • D. Electron-pair donor
Answer: D
Explanation: Lewis bases donate electron pairs.

NEET Chemistry · Thermodynamics · Very Very Hard

12. For a first-order kinetic process in Thermodynamics, half-life equals:

  • A. 0.693/k
  • B. k/0.693
  • C. 1/(k[A]0)
  • D. [A]0/(2k)
Answer: A
Explanation: First-order t1/2=0.693/k.

NEET Chemistry · Thermodynamics · Very Very Hard

13. The Arrhenius equation is:

  • A. k=Ae^(Ea/RT)
  • B. k=EaRT
  • C. k=A/RT
  • D. k=Ae^(-Ea/RT)
Answer: D
Explanation: Arrhenius equation relates k to activation energy and temperature.

NEET Chemistry · Thermodynamics · Very Very Hard

14. For an ideal dilute solution relevant to Thermodynamics, molarity is:

  • A. Grams solute per mole solvent
  • B. Moles solvent per litre
  • C. Moles solute per litre solution
  • D. Moles solute per kg solvent
Answer: C
Explanation: M=n/V(L).

NEET Chemistry · Thermodynamics · Very Very Hard

15. For a weak acid, a larger Ka generally indicates:

  • A. A stronger conjugate acid
  • B. A stronger acid
  • C. A weaker acid
  • D. No ionisation
Answer: B
Explanation: Larger Ka means greater ionisation.

NEET Chemistry · Thermodynamics · Very Very Hard

16. At 25°C, pH+pOH for aqueous solution is:

  • A. 14
  • B. 7
  • C. 1
  • D. 0
Answer: A
Explanation: pH+pOH=pKw=14 at 25°C.

NEET Chemistry · Thermodynamics · Very Very Hard

17. For an electrochemical cell, oxidation occurs at:

  • A. Cathode
  • B. Salt bridge
  • C. Electrolyte only
  • D. Anode
Answer: D
Explanation: Oxidation occurs at the anode.

NEET Chemistry · Thermodynamics · Very Very Hard

18. For an electrochemical cell, reduction occurs at:

  • A. Salt bridge
  • B. Wire
  • C. Cathode
  • D. Anode
Answer: C
Explanation: Reduction occurs at the cathode.

NEET Chemistry · Thermodynamics · Very Very Hard

19. An electrophile in an organic reaction related to Thermodynamics is:

  • A. Always negatively charged
  • B. Always a radical
  • C. Electron-pair acceptor
  • D. Electron-pair donor
Answer: C
Explanation: Electrophiles accept electron pairs.

NEET Chemistry · Thermodynamics · Very Very Hard

20. The inductive effect in Thermodynamics is transmitted mainly through:

  • A. Ionic lattice only
  • B. Sigma bonds
  • C. Pi bonds only
  • D. Hydrogen bonds
Answer: B
Explanation: Inductive polarization is transmitted through sigma bonds.

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Thermodynamics Practice Tests

Thermodynamics Frequently Asked Questions

What causes most Thermodynamics mistakes?

Sign conventions for heat and work, confusing state functions with path functions, and using inconsistent units are common sources of error.

What does negative ΔG indicate?

For a process under the stated conditions, negative Gibbs free-energy change indicates thermodynamic spontaneity.

How should I revise Thermodynamics?

Build a one-page sign-convention and formula sheet, then practise problems that require choosing the correct relation rather than only substituting numbers.

Continue with another chapter to build connected concepts and strengthen your overall Chemistry preparation.

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